Showing posts with label water. Show all posts
Showing posts with label water. Show all posts

Tuesday, January 18, 2011

Mpemba Effect



Water is just mundane and seems well-understood in many respects. However, there are still quite a lot of things that motivate people to find more. For example, how water molecules arrange themselves when they adsorbed on an adsorbate. Another instance is, I think more associated with the thermodynamics of water: it has been claimed that, hot water cools faster than cold water when they are placed in the same chamber. This was named after its discoverer, a middle school student Mpemba. There came a latest study on this [http://arxiv.org/ftp/arxiv/papers/1101/1101.2684.pdf]:
In this paper we have presented data confirming that water initially at higher temperature cools at a faster rate than water initially at a lower temperature and that this trend continues past the point at which the two samples reach the same temperature: the crossover temperature. Furthermore, our data indicates that the starting temperature affects the crossover temperature in a reproducible manner. We have confirmed that warmer water indeed cools faster than colder water and that, surprisingly, this trend continues past the point where the temperatures of the two samples are the same. Our results show that when using optimal initial temperature conditions, the crossover temperature is found to be 2.7 oC whereas our other set of initial conditions gave a crossover temperature of -0.07 oC. These data taken together provide a definite quantitative evidence of the Mpemba effect.

Tuesday, August 31, 2010

confined water

The properties of water under conventional conditions are largely known to scientists. But those under unusual cases are rarely revealed. One example is, what happens to the viscosity and elasticity of water confined to two solids in thin layer of nanometer? According to a recent study[1], there may happen a solid-like transition with respect to the rate at which the two solids approach each other, that is, elasticity increases while viscosity decreases.
[1]Phys. Rev. Lett. 105, 106101 (2010)
Schematic illustration of a confined fluid. Imagine that a liquid droplet is placed between a ball and a flat surface, and a ball is allowed to fall (right panel) onto it. When the thickness of the liquid is plotted schematically against time after the ball begins to fall, the film thickness remains finite at equilibrium (bottom left panel). This is because fluid tends to layer parallel to the solid surfaces. When the local liquid density is plotted against the distance between the solid boundaries, it shows decaying oscillations with a period of about a molecular dimension (top left panel). When these density waves shown in the bottom panel come sufficiently close to interfere with one another, the liquid can support force at equilibrium.

Wednesday, August 18, 2010

snowflakes

Oh, man, I love this diagram:

http://www.its.caltech.edu/~atomic/publist/rpp5_4_R03.pdf