Metastable states are important in reality

Metastable states are common in nature: supercooled or superheated liquid are daily examples. These states are not the lowest-energy state, and, by thermodynamic principles, one should not expect them to be long-lived in nature. Indeed, they exist only under very stringent conditions, and very little disturbance can push the system off to a stable state around. Thermodynamically stable states dwell on one of the global minima of the free energy, around which, however, local minima might exist that are separated from the global minima by energy barriers. When a system has not reached the stable states, it will be constantly kicked by its surroundings and eventually transits from where it is in to a stable state after some period (the life of the metastable state). The interesting point is that, the life time can sometimes be very long and real transitions can hardly be seen, a situation similar to ergodicity breaking. For example, diamond has a higher energy than graphite, but it can exist for ever. The reason is because the time to make the transition is cosmologically long, due to the hugely high barrier. Another material is graphene, which should not be stable according to Wagner-Mermin-Honberg theorem. Yet, it was produced in 2004. Glasses are the third examples, in which case, transition has been frustrated by its structure. In the case of supercooled water, the transition is suppressed by distilling process.